Electrochemical study of TiO2 in aqueous AlCl3 electrolyte via vacuum impregnation for superior high-rate electrode performance

This communication elucidates the charge storage mechanism of a TiO 2 electrode in 1 mol dm − 3 AlCl 3 for use in aqueous-ion batteries. Cyclic voltammetry studies suggest a surface contribution to charge storage and that cycle life can be improved by limiting the potential ≥ − 1.0 V vs SCE. In order to enhance this surface contribution, a simple vacuum impregnation technique was employed to improve electrode-electrolyte contact. This resulted in a significant improvement in the high rate performance of TiO 2 , where a capacity of 15 mA h g − 1 was maintained at the very high specific current of 40 A g − 1 , a decrease of only 25% from when the electrode was cycled at 1 A g − 1 . The vacuum impregnation process was also applied to copper-hexacyanoferrate, envisaged as a possible positive electrode, again resulting in significant improvements to high-rate performance. This demonstrates the potential for using this simple technique for improving electrode performance in other aqueous electrolyte battery systems.


Introduction
Asymmetric and hybrid devices based on a combination of capacitive, psuedocapacitive or battery intercalation electrodes have gained interest lately due to performance characteristics that could bridge the gap between the high energy density of Li-ion chemistries and high power of supercapacitors. Furthermore, there is interest in the use of aqueous electrolytes, which can provide advantages in terms of cost, ease of handling, toxicity, and environmental benignity. The use of electrolytes based on Na, K or Al salts also benefit from the higher natural abundance and relative ease of processing of these materials compared to Li salts and organic solvents.
Excluding Li-ion, negative electrodes for aqueous metalion systems are relatively limited with NaTi 2 (PO 4 ) 3 and metallic Zn commonly used in aqueous Na-ion and Znion cells [1][2][3][4]. Similarly, while a variety of positive electrodes have been explored for aqueous super/psuedocapacitors, such as MnO 2 [5][6][7], RuO 2 [8][9][10], Ni (OH) 2 [11], Co (OH) 2 [12], Co 3 O 4 [13] or Prussian blue analogues [14,15], the number of negative electrodes is far lower. As such, a non-exhaustive review of aqueous super/ pseudo-capacitive devices, reported since 2014, shows that the majority of negative electrodes consist of activated carbon (AC) or other carbon-based materials, as shown in Additional file 1: Table S1. A recent review on asymmetric supercapacitors by Shao et al., further illustrates this, where the majority of studies and devices make use of AC, graphene or graphene oxide as the negative electrode [16]. The use of AC is likely to limit cell voltage and capacity while graphene materials can result in high cost and low scalability. TiO 2 provides a possible option for a negative electrode, having been studied in aqueous aluminium salt electrolytes and shown to have working potentials lower than ca. < − 0.5 V vs SCE [15][16][17][18][19][20], presenting the opportunity for dual-ion devices working at higher voltages [21][22][23][24]. TiO 2 nanotube arrays, synthesised by Liu et al., allowed a capacity of ca. 75 mA h g − 1 when cycled at 4 mA cm − 2 in 1 mol dm − 3 AlCl 3 [17]. He et al., have provided evidence for Al 3+ intercalation, where XRD analysis showed anatase-TiO 2 lattice parameters changing with state-of-charge [19]. However, capacitive or surface contributions to charge storage cannot be entirely ruled out, especially at high rates. For example, cathodic redox peaks from TiO 2 , associated with Al 3+ insertion, are at more negative potentials than the plateaus observed during constant current cycling [17,19,20]. Furthermore, a graphene incorporated TiO 2 electrode studied by Lahan et al., provided a capacity of approximately 20 mA h g − 1 at 6.25 A g − 1 , though the electrode showed very limited redox peaks during CV scans, suggesting the possibility of a capacitive or psuedocapacitive mechanism [1]. Previous work has also shown high rate capability, up to 360 C (7.2 A g − 1 ), from commercial TiO 2 nanopowders, though relatively low capacities were measured [25].
Building upon previous work, this communication elucidates the charge storage mechanism of commercial TiO 2 powder electrodes in 1 mol dm − 3 AlCl 3 and demonstrates a TiO 2 electrode capable of stable cycling at 40.0 A g − 1 with close to 100% charge efficiency.

Experimental procedures
TiO 2 electrodes were manufactured using a 5 nm TiO 2 powder purchased from US-nano. Electrodes consisted of 85 wt% TiO 2 , 5 wt% carbon black (Vulcan 72-CR), 6 wt% Nafion and 4 wt% PTFE. TiO 2 , carbon black, Nafion and propanol (approximately 3 g for 1 g dry powder) were mixed using a Silverson high speed shear mixer at 5000 rpm for 30 min. PTFE was then added with the ink sonicated for a further 15 min. The ink is coated onto carbon polymer (Sigracell PV15) current collectors with excess allowed to drip off before being laid flat to dry in ambient conditions. Once dry, additional layers were added to manufacture electrodes with mass loadings as high as 6.5 mg cm − 2 covering an area of 7 cm 2 .
Brunauer-Emmett-Teller (BET) surface area and pore size distribution were calculated from N 2 adsorptiondesorption isotherms, measured at − 196°C, using a Gemini 2375 analyser.
Cyclic voltammetry and constant current cycling were performed in standard glass 3-electrode cells using a saturated calomel electrode (SCE) as reference and an oversized CuHCF, typically 7-8 times by mass, as a reversible counter electrode. Cyclic voltammetry was performed in 1 mol dm − 3 AlCl 3 while constant current cycling was performed in an electrolyte comprising 1 mol dm − 3 AlCl 3 and 1 mol dm − 3 KCl. A solartron 1470E battery analyser was used for constant current cycling while cyclic voltammetry was performed on an Ivium-n-Stat potentiostat.
Vacuum impregnation, previously used by Yong et al. for impregnation of textile supercapacitor electrodes [26], was performed using the experimental set-up shown in Fig. 1a with a proposed schematic of how electrolyte is forced into electrode pores being presented in Fig. 1b. This method was performed by placing electrodes, submerged in the electrolyte of 1 mol dm − 3 AlCl 3 /1 mol dm − 3 KCl, in a Buchi tube. A filtration vacuum pump was used to create a vacuum of 20 mbar within the tube for approximately 15 min. The air vent was then opened, letting air in, before the process was repeated a further three times by which point air bubbles were no longer visible at the electrode surface.
Results and discussion Figure 2a shows the N 2 adsorption-desorption BET isotherm from the TiO 2 nanopowder. The BET surface area was calculated to be 269 m 2 g − 1 . The profile resembles a type IV isotherm according to the IUPAC classification. Fig. 2b shows a pore size distribution between 25 Å to 100 Å with a dominant peak at around 55 Å. This corresponds well with the isotherm in Fig. 2a, which demonstrates the mesoporous nature (2 nm -50 nm) of the powder.
Cyclic voltammetry of two TiO 2 electrodes was performed at various scan rates, ν, in 1 mol dm − 3 AlCl 3 aqueous solution. One electrode was scanned between 0 V to − 1.3 V vs SCE and the other between the potential range of 0 V to − 1.0 V vs SCE. By limiting the potential window, charge storage may be limited to a capacitive or surface controlled mechanism. Figure 3a presents the profiles measured from TiO 2 at the 5th, 18th and 25th cycles when swept between the extended potential range of 0 V to − 1.3 V vs SCE. Between the 5th and 18th cycle there is small reduction in the cathodic peak, from − 13.0 A g − 1 to − 11.8 A g − 1 , while the anodic peak potential shifts from − 1.03 V, during the 10th scan, to − 0.97 V vs SCE during the 18th. Figure 3b shows the profile from TiO 2 during the 5th, 25th and 80th scan at 10 mV s − 1 between 0 V to − 1.0 V vs SCE. The profiles can be seen to be nearly identical irrespective of scan number, suggesting improved stability from TiO 2 when cycled at a more positive minimum potential. Figure 4a shows the CV scans at 3, 9 and 16 mV s − 1 between 0 V to − 1.3 V vs SCE. The profile shapes at these three scan rates closely resemble each other. During the cathodic sweep, current curves down between − 0.55 V to − 0.95 V where there is a brief plateau till ca. -1.1 V. The current curves down to a prominent peak between − 1.15 V and − 1.20 V vs SCE. At 3 mV s − 1 , the reverse sweep gives rise to a prominent peak at − 1.05 V. The position of this peak becomes more positive with increasing scan rate with peak position being approximately − 0.95 V at 16 mV s − 1 . As with the cathodic sweep, the anodic sweep gives rise to a slight shoulder and plateaubetween ca. -0.9 V and − 0.75 V, when current drops steadily to zero at approximately − 0.5 V. Fig. 4b gives the peak currents against the square root of the scan rates. A linear fit, with an x-y intercept set to zero, shows there is an approximately linear relationship between the measured current and square root of the scan rate for both cathodic and anodic sweeps. A linear relationship suggests a diffusion-limited process, as described by the power law given by equation… (1), where a and b are adjustable values, i is the measured current and ν the scan rate [27,28].
A b-value of 0.5 is often measured from intercalation electrodes, with the measured current limited by the solid-state diffusion (intercalation) of the cation through the electrode. This may be true for the case of TiO 2 and Al 3+ , given the use of a relatively high concentration electrolyte, which should negate the possibility of a reaction being limited by the diffusion of Al 3+ through the electrolyte to the electrode surface.
However, the greater stability of TiO 2 when scanned with the more positive minimum potential of − 1.0 V vs SCE, compared to − 1.3 V, suggests the possibility of a separate charge storage mechanism compared to when the electrode is scanned to − 1.3 V. That is, the redox reaction of Ti 4+ to Ti 3+ may only take place once more negative potentials are reached. As such, further CV scans were performed between 0 V to − 1.0 V vs SCE. Fig. 4c shows these CV profiles at scan rates between 2 mV s − 1 to 100 mV s − 1 , normalised by scan rate. That the profiles do not fall onto a single profile means that charge storage in this potential range is not purely capacitive. Further analysis of the CV profiles can be performed by calculating the capacity of the electrodes at different scan rates. This technique has previously been used in the literature with materials, such as Nb 2 O 5 , NiCo 2 O 4 , LaB 6 , conductive polymers and for Li + insertion into mesoporous titania [29][30][31][32]. The analysis can provide an indication of charge storage arising from bulk or surface mechanisms at given scan rates. Fig. 4d shows the cathodic and anodic voltammetric capacities against ν -1/2 . For the cathodic charge input, the volumetric capacity is linearly proportional to ν -1/2 at scan rates up to 30 mV s − 1 , (0.182 mV s − 1 ) -1/2 . Extrapolation of the linear fit to 0 (mV s − 1 ) -1/2 suggests a surface charge storage contribution of approximately 12 mA h g − 1 . Therefore, at a scan rate of 10 mV s − 1 , for example, the surface contribution to capacity would be approximately 50%. The remaining charge could then be the result of a bulk process such as intercalation. Alternatively, it could suggest there are areas of the electrode, such as narrow pores, that are difficult to access. At scan rates above 30 mV s − 1 , the charge vs ν -1/2 plot deviates from linearity, suggesting a change in the rate-limiting charge storage process or that charge storage is almost entirely dominated by a semi-infinite diffusion. At lower scan rates, between 2 to 30 mV s − 1 , the extrapolation of the linear dependence of cathodic capacity vs ν -1/2 , to approximately 12 mA h g − 1 , suggests that charge storage is diffusion controlled. Given the low capacities, it is still unlikely that this diffusion limitation is a result of Al 3+ intercalation through the crystal structure of anatase-TiO 2 but may instead be due to the limited diffusion of electrolyte and Al 3+ , due to the short time constants at these high scan rates, through the electrodes pores. While there may be a capacitive contribution, as deduced from the extrapolation of the infinite scan rate capacity, the nonconformity of the normalised scan rates suggests there is also a diffusion controlled charge storage mechanism.
The existence of a surface controlled storage mechanism, along with the mesoporous structure of the 5 nm TiO 2 powder (Fig. 2), suggests performance can be improved through greater electrolyte-electrode contact. In order to achieve this, a simple vacuum impregnation technique was employed to ensure proper electrode wetting. The experimental set-up and proposed schematic of forced electrode wetting were presented in Fig. 1. It is proposed that electrode pores previously inaccessible to electrolyte, due to surface tension and the hydrophobicity of the nanopowder electrode, are filled with electrolyte due to the removal of air and creation of low pressure voids within the electrode. Constant current cycling was then performed on a vacuum impregnated electrode in a 3electrode cell between 0.4 V to − 1.0 V vs SCE. The coulombic efficiency and discharge capacity of the vacuum impregnated electrode when cycled at specific currents between 0.2 to 40.0 A g − 1 is shown in Fig. 5a. The figure shows the 10th cycle at a given specific current between cycles 70-120 for as-manufactured TiO 2 and cycles 70-200 for impregnated TiO 2 . For comparison, the performance of an as-manufactured electrode, when cycled up to 6.0 A g − 1 , is also shown in Fig. 5a. Additional file 1: Figure  S1 shows the discharge capacity and coulombic efficiency of the two electrodes vs cycle number. Between 0.2 A g − 1 and 1.0 A g − 1 , discharge capacity from the vacuum impregnated electrode decreases from 21.8 mA h g − 1 to 19.8 mA h g − 1 , with coulombic efficiency increasing from 89.8 to 96.9%. At 2.0 A g − 1 , coulombic efficiency was 99.4%, though discharge capacity was also measured at 19.8 mA h g − 1 . Between 1.0 A g − 1 to 25 A g − 1 , discharge capacity At 40.0 A g − 1 , discharge capacity was measured at 15.3 mA h g − 1 . Above 2.0 A g − 1 , coulombic efficiency remained around 99.9%, though some error will be present due to the rapid charge discharge times, i.e. at 40.0 A g − 1 discharge occurs in 1.43 s, even at the used measurement rate of 80 data points per second. Coulombic efficiency of an as-manufactured electrode is lower throughout and while discharge capacity is comparable up to 2.0 A g − 1 , once cycled at 6.0 A g − 1 , discharge capacity was measured at 15.7 mA h g − 1 compared to 19.33 mA h g − 1 for the vacuum impregnated electrode. The voltage profiles from the vacuum impregnated electrode between 1.0 A g − 1 to 40 A g − 1 are given by Fig. 5b. Voltage profiles can be seen to be similar, irrespective of the specific current used. The initial IR-drop at 1 A g − 1 is minimal, being less than 10 mV and only becoming noticeable at higher specific currents. At 10.0 A g − 1 , the IR-drop is measured as 44 mV, increasing to 162 mV at 40.0 A g − 1 , with the average charge and discharge potentials at 40.0 A g − 1 being − 0.826 V and − 0.627 V, respectively. For comparison, the IR drop from the asmanufactured electrode at 6 A g − 1 was already 124 mV. The results presented in Fig. 5 show a clear improvement in rate capability of electrodes subjected to the vacuum impregnation technique. This specific currents reached are considerably higher than have been previously reported for TiO 2 in aqueous Al 3+ -containing electrolytes. It should also be noted that the experiment was performed on an electrode with a relatively high mass loading of 6.5 mg cm − 2 , so that the corresponding current density at 40 A g − 1 is a very high value of 260 mA cm − 2 . In comparison, capacities of 50 mA h g − 1 and ca. 62 mA h g − 1 were Fig. 4 (a) and (b) give the CV scans and peak currents from TiO 2 , in 1 mol dm − 3 AlCl 3 , at scan rates between 3 mV s − 1 to 16 mV s − 1 between potentials limits of 0 V to − 1.3 V vs SCE. c and d give the normalised CV scans and peak currents from TiO 2 at scan rates between 2 mV s − 1 to 100 mV s − 1 with potential limits set between 0 V to − 1.0 V vs SCE measured from MnHCF (positive) and graphene (negative) electrodes were achieved at the current density of 5 mA cm − 2 in LiNO 3 [33,34]. These capacities and current densities are toward the maximum reported for aqueous capacitive devices. Furthermore, the relative stability of the voltage profiles and capacity, where discharge capacity drops by < 25% over an order of magnitude increase in specific current, provides evidence that charge storage from these TiO 2 electrodes in aqueous Al 3+ electrolyte are predominantly capacitive or controlled by surface reactions at high currents, similar to psuedocapacitive materials. However, care should be taken in describing TiO 2 as psuedocapacitive given the relatively clear voltage plateaus observed during constant current cycling, in aqueous Al 3+ -containing electrolytes, which is in contrast to the electrochemical characteristics of a capacitor. The vacuum impregnation process was also repeated on a CuHCF electrode, envisaged as a potential positive electrode, with the effect on voltage profiles and capacities at various rates shown in Additional file 1: Figure S2. Capacity from the vacuum impregnated electrode, which had a mass loading of 8.8 mg cm − 2 , was measured at 47.08 mA h g − 1 at 0.5 A g − 1 and maintained a capacity of 28.2 mA h g − 1 at 8 A g − 1 . The capacity of the as-manufactured CuHCF electrode, with a mass loading of 8 mg cm − 2 , was 44.42 mA h g − 1 at 0.5 A g − 1 and decreased to 14.1 mA h g − 1 at 6 A g − 1 . The results demonstrate the applicability of the vacuum impregnation process for improving the performance of alternative electrodes.

Conclusions
Analysis of the CV response from TiO 2 at different scan rates suggested the contribution of a surface controlled charge storage mechanism. Enhancing this surface contribution was achieved through the application of a vacuum impregnation technique to achieve good electrode wetting and improve electrode-electrolyte contact. This vacuum impregnation step allowed a 1.5 cm × 2 cm, 6.5 mg cm − 2 TiO 2 electrode to maintain a capacity of 15 mA h g − 1 at the very high specific current of 40 A g − 1 with potential hysteresis between charge and discharge being only 200 mV. A 25% drop in capacity over an order of magnitude increase in specific current adds further evidence to the presence of a surface controlled or capacitive charge storage mechanism from the TiO 2 electrode. The results demonstrate the considerable performance improvements possible from this simple vacuum impregnation technique.

Funding
This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No 646286. This contribution was financial only and did not include design of the study or collection, analysis, and interpretation of data or writing the manuscript.
Availability of data and materials Supporting data and background material can be found in the accompanying supplementary material document.